Wednesday, February 18, 2015

Alessandro Volta(father of electrical battery)

Alessandro Giuseppe Antonio Anastasio Volta (18 February 1745 – 5 March 1827) was an Italian physicist  credited with the invention of the first electrical battery, the Voltaic pile, which he invented in 1799 and the results of which he reported in 1800 in a two part letter to the President of the Royal Society.With this invention Volta proved that electricity could be generated chemically and debased the prevalent theory that electricity was generated solely by living beings. Volta's invention sparked a great amount of scientific excitement and led others to conduct similar experiments which eventually led to the development of the field of electrochemistry.

The battery made by Volta is credited as the first electrochemical cell. It consists of two electrodes: one made of zinc, the other of copper. The electrolyte is either sulfuric acid mixed with water or a form of saltwater brine. The electrolyte exists in the form 2H+ and SO42−. The zinc, which is higher than both copper and hydrogen in the electrochemical series, reacts with the negatively charged sulfate (SO42−). The positively charged hydrogen ions (protons) capture electrons from the copper, forming bubbles of hydrogen gas, H2. This makes the zinc rod the negative electrode and the copper rod the positive electrode.
Thus, there are two terminals, and an electric current will flow if they are connected. The chemical reactions in this voltaic cell are as follows:
zinc
Zn  Zn2+ + 2e
sulfuric acid
2H+ + 2e  H2
The copper does not react, but rather it functions as an electrode for the electric current.

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